Adsorption Equilibrium of Nitrates Ions onto Oil Palm Shells-based Activated Carbons
activated carbons; isotherms; nitrates; oil-palm shells; physicochemical activation
Abstract
In this study, two oil palm shells-based activated carbon adsorbents were prepared by physicochemical activation and were evaluated for their ability to remove nitrate ions from an aqueous solution in a batch process. Steam was used as physical activation agent in combination with H 3 PO 4 and KOH as chemical activating agents, respectively. The H 3 PO 4 -carbon (ACOPS-H 3 PO 4 ) and the KOH-carbon (ACOPS-KOH) oil palm shell activated carbons had a BET surface area of 564 and 838 m 2 /g, respectively, and were essentially microporous. The effects of various parameters such as contact time, initial solution pH and adsorbent dosage on nitrate ions uptake were investigated. The experimental results obtained showed that the adsorption equilibrium was reached within 70 mn. The amount of nitrate intake was observed to gradually increase when the amount of adsorbent used was varied from 0.2 to 1.2 g reaching a maximum value as from 1 g of adsorbent.
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C Namasivayam, D Sangeetha (2005) Kinetic studies of adsorption of thiocyanate onto ZnCl2 activated carbon from coir pith, an agricultural solid waste. 60(11), 1616-1623.
K Kumar, C Calahorro, J Juarez, M Sabio, J Albero, F Reinoso (2010) Hybrid isotherms for adsorption and capillary condensation of N 2 at 77 K on porous and non-porous materials. 162, 424-429.
K Foo, B Hameed (2012) Textural porosity, surface chemistry and adsorptive properties of durian shell derived activated carbon prepared by microwave assisted NaOH activation. 187, 53-62.
K Foo, B Hameed (2012) Coconut husk derived activated carbon via microwave induced activation: Effects of activation agents, preparation parameters and adsorption performance. 184, 57-65.
S Mak, B Tey, K Cheah, W Siew, K Tan (2009) Porosity characteristics and pore developments of various particle sizes palm kernel shells activated carbon (PKSAC) and its potential applications. 15(5-6), 507-519.
I Tan, A Ahmad, B Hameed (2008) Adsorption of basic dye on high-surface-area activated carbon prepared from coconut husk: Equilibrium, kinetic and thermodynamic studies. 154, 337-346.
A Shahsavand, M Shahrak (2011) Reliable prediction of pore size distribution for nano-sized adsorbents with minimum information requirements. 171(1), 69-80.
J Sahira, A Mandira, P Prasad, P Ram (2013) Effects of activating agents on the activated carbons prepared from Lapsi seed stone. 3(5), 19-24.
J Guo, A Lua (2003) Textural and chemical properties of adsorbent prepared from palm shell by phosphoric acid activation. 80, 114-119.
I Tan, A Ahmad, B Hameed (2008) Adsorption of basic dye on high-surface-area activated carbon prepared from coconut husk: Equilibrium, kinetic and thermodynamic studies. 154(1-3), 337-346.
Morteza Mohsenipour, Shamsuddin Shahid, Kumars Ebrahimi (2015) Nitrate Adsorption on Clay Kaolin: Batch Tests. 2015(1), 397069.
Mahmoud El Ouardi, Samir Qourzal, Said Alahiane, Ali Assabbane, Jamaa Douch (2015) Effective Removal of Nitrates Ions from Aqueous Solution Using New Clay as Potential Low-Cost Adsorbent. 05(04), 178-190.
Neşe Öztürk, T Bektaş (2004) Nitrate removal from aqueous solution by adsorption onto various materials. 112(1-2), 155-162.
S Chatterjee, D Lee, M Lee, S Woo (2009) Enhanced adsorption of congo red from aqueous solutions by chitosan hydrogel beads impregnated with cetyltrimethyl ammonium bromide. 100, 2803-2809.
A Aljeboree, A Alshirifi, A Alkaim (2014) Kinetics and equilibrium study for the adsorption of textile dyes on coconut shell activated carbon.
S Senthilkumaar, P Kalaamani, K Porkodi, P Varadarajan, C Subburaam (2006) Adsorption of dissolved Reactive red dye from aqueous phase onto activated carbon prepared from agricultural waste. 97(14), 1618-1625.
B Singh, Y Kanehiro (1969) Adsorption of nitrate in amorphous and kaolinitic Hawaiian soils. 681-683.
M Elouardi, S Qourzal, S Alahiane, A Assabbane, J Douch (2015) Effective removal of nitrates ions from aqueous solution using new clay as potential lowcost adsorbent. 5, 178-190.
Dae Sudiptachatterjee, Min Lee, Lee, H Seung, Woo (2009) Enhanced adsorption of congo red from aqueous solutions by chitosan hydrogel beads impregnated with cetyltrimethyl ammonium bromide. 100, 2803-2809.
Irving Langmuir (1916) THE ADSORPTION OF GASES ON PLANE SURFACES OF GLASS, MICA AND PLATINUM.. 40(9), 1361-1403.
Irving Langmuir (1918) THE ADSORPTION OF GASES ON PLANE SURFACES OF GLASS, MICA AND PLATINUM.. 40(9), 1361-1403.
Moonis Khan, Yong-Tae Ahn, Mahendra Kumar, Wontae Lee, Booki Min, Gyoobum Kim, Dong-Wan Cho, Won Park, Byong-Hun Jeon (2011) Adsorption Studies for the Removal of Nitrate Using Modified Lignite Granular Activated Carbon. 46(16), 2575-2584.
Odivan Zanella, Isabel Tessaro, Liliana Féris (2015) Nitrate sorption on activated carbon modified with CaCl2: Equilibrium, isotherms and kinetics. 21(1-1), 23-33.
Dinesh Mohan, Subhash Chander (2006) Single, binary, and multicomponent sorption of iron and manganese on lignite. 299(1), 76-87.
C Giles, T Macewan, S Nakhwa, D Smith (1960) 786. Studies in adsorption. Part XI. A system of classification of solution adsorption isotherms, and its use in diagnosis of adsorption mechanisms and in measurement of specific surface areas of solids. 3973.
S Rengaraj, Seung-Hyeon Moon, R Sivabalan, B Arabindoo, V Murugesan (2002) Agricultural solid waste for the removal of organics: adsorption of phenol from water and wastewater by palm seed coat activated carbon. 22(5), 543-548.
Ying Zhang, Xiao-Lan Song, Shu-Tao Huang, Bai-Yang Geng, Chi-Hsien Chang, I-Yen Sung (2014) Adsorption of nitrate ions onto activated carbon prepared from rice husk by NaOH activation. 52(25-27), 4935-4941.
R Elmoubarki, F Mahjoubi, H Tounsadi, J Moustadraf, M Abdennouri, A Zouhri, A Elalbani, N Barka (2015) Adsorption of Textile Dyes on Raw and Decanted Moroccan Clays: Kinetics, Equilibrium and Thermodynamics. 9, 16-29.
Yuanyuan Sun, Qinyanyue, Bo Baoyugao, Qian Wang, Lihui Li, Xing Huang, Xu Comparison of activated carbons from Arundodonax Linn with H 4 P 2 O 7 activation by conventional and microwave.
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2018-05-04
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