Kinetic and Thermodynamic study for Adsorption a Desorption of Diazinon with copper in the presence of Surfactant
Adsorption- desorption isotherms, Copper, Diazinon, HPLC, Surfactant
Abstract
In the present work change in the adsorption-desorption processes of Diazinon [O,Odiethylo-(2-isopropyl-6-methyl4pyrimidinyl) phosphorothioate] which is nonionicorganophosphorous pesticide, preformed by using batch equilibrium experiments on six agricultural soil samples. The kinetics study for adsorption processes investigated that first order rate law and power function equation model provided the best correlation with experiment results. The isothermal models Linear, Freundlich, and Langmuir were applied to describe the adsorption-desorption affinities to the soils. Thermodynamic parameters (ΔG, ΔH and ΔS) were also calculated according to the values of binding Langmuir constant K L at 10, 25, 40 ±1ºC. Linear coefficient K d values for adsorption process of diazinon varied between 3.261 -6.413 mlg-1. Freundlich coefficient KF values for adsorption process varied between 1.194 -1.506 mlg -1 . Langmuir coefficient KL for adsorption process varied between 0.017 -0.020 mlg -1 . The negative values for each of ΔG, ΔH and ΔS constants confirmed that diazinon adsorption processes more at lower temperature and done via enthalpy effect.
Downloads
How to Cite
References
Ching-Hua Huang, Alan Stone (1999) Hydrolysis of Naptalam and Structurally Related Amides: Inhibition by Dissolved Metal Ions and Metal (Hydr)Oxide Surfaces. 47(10), 4425-4434.
D Kramen, R Gamson (1975) Analysis of toxic phosphorus compounds. 29, 21A.
L Rhodes (1987) Ferrari) (Coleoptera: Scolytidae). 122.
(2000) Diazinon phaseout affects home, lawn uses. 2320-2321.
Iglesias-Jimeneze (1997) Sorption of Linuron and diazinon. 33, 117.
M Sánchez, R Méndez, X Gómez, J Martín‐villacorta (2003) Determination of Diazinon and Fenitrothion in Environmental Water and Soil Samples by HPLC. 26(3), 483-497.
T David, Williams, Guyl Cathy Shewchuck, Nancy Lebel, Muir (1987) Diazinon levels in door air after periodic application for insect control. 48(9), 780-785.
T S Poet, H Wu, A Kousba, C Timchalk (2003) In vitro rat hepatic and intestinal metabolism of organophosphate pesticides chlorpyrifos and diazinon. 72, 193-200.
D Larkin, R Tjeerdema (2000) Fate and effects of diazinon. 166, 49-82.
Op, Bansal (2004) Kinetics of Interaction of three Carbamate Pesticides with Indian soils: Aligarh district. 60, 1149-1155.
Rounakm. Shariff, Kafiam. Shareef (2011) Adsorption of Herbicides on eight Agricultural Soils. 3(2), 67-75.
E Morillo, T Undabeytia, C Maqueda, A Ramos (2000) Glyphosate adsorption on soils of different characteristics.. 40(1), 103-107.
J Hamaker (1967) The Application of Mathematical Modeling to the Soil Persistence and Accumulation of Pesticides. 181-199.
David Di Cesare, James Smith (1994) Surfactant Effects on Desorption Rate of Nonionic Organic Compounds from Soils to Water. 134, 1-29.
A Mohammed, Peter Ali, Baugh (2003) Sorption, Desorption Studies of Six Pyerethroids and Mirex on Soils using GC/ MS-NICI " Internet. 83(11), 923-933.
M Shariff (2011) The Study of Adsorption and Desorption of Picloram on six Agricultural Soils. 3(3), 13-24.
M Shariff (2012) Thermodynamic Adsorption-desorption of Metolachlor and 2,4-D on Agricultural Soils. 3(4), 55-69.
G Suman, V Gajbhiye (2002) Adsorptiondesorption, presestance, and leaching beahavior of dithiopyr in an auuvial soil of India. 37(6), 573-586.
K Sundaram, J Curry, M Landmark (1995) Sorptive behavior of the neem-based biopesticide, azadirachtin, in sandy loam forest soil. 30(6), 827-839.
Marcelo Kogan, Alejandra Metz, Rodrigo Ortega (2003) Adsorption of glyphosate in chilean soils and its relationship with unoccupied phosphate binding sites. 38(4), 513-519.
Adolphe Monkiedje, Michael Spiteller (2002) Sorptive behavior of the phenylamide fungicides, mefenoxam and metalaxyl, and their acid metabolite in typical Cameroonian and German soils. 49(6), 659-668.
R Griffin, J Jurinak ; Elsayed, A Elkhatib, A Mahdy, N Bbrakat (2007) Thermodynamics of Copper Desorption from Soils as Affected by Citrate and Succinate. 2(4), 135-140.
K Chaudhary, B Prasad (1999) Thermodynamics of Potassiume Exchange Reaction in Entisol and vertisol using a Kinetic Approach by Miscible Displacement Technique. 47(2), 221-229.
H Selim, H Zhu (2005) Organic Compounds in Environment Atrazine Sorption-Desorption Hysteriesis by Sugarca Mulch Residue. 34, 325-335.
Cass Miller, Joseph Pedlt (1992) Sorption-Desorption Hysteresis and Abiotic Degradation of Lindane in a Surface Material. 26, 1417-1427.
H Xinjiang, M Thomas (2005) Unknown Title. 95616.
Hrissi Karapanagioti, Sybille Kleineidam, David Sabatini, Peter Grathwohl, Bertrand Ligouis (2000) Impacts of Heterogeneous Organic Matter on Phenanthrene Sorption: Equilibrium and Kinetic Studies with Aquifer Material. 34(3), 406-414.
George Bailey, Joe White (1970) Factors influencing the adsorption, desorption, and movement of pesticides in soil. 30, 29-92.
M Shariff (2011) Thermodynamic Adsorptiondesorption of Metolachlor and 2,4-D on Agricultural Soils. 3(4), 134-146.
A Elsayed, A Elkhatib, N Mahdy, Bbrakat (2007) Thermodynamics of copper desorption from soils as affected by citrate and succinate. 2(4), 135-140.
Daniel Said‐pullicino, Giovanni Gigliotti, Alfred Vella (2004) Environmental Fate of Triasulfuron in Soils Amended with Municipal Waste Compost. 33(5), 1743-1751.
A Cludio, Arthur Spadotto, Hornsby (2003) organic compounds in the environment soil sorption of acidic pesticides: modeling pH effects. 32, 949-956.
Deenise Jeong -Hunpark, Xianda Kuy, Stephen Zhao, Thomas Boyed, Vocie (2001) Kinetic modeling of bioavailability of sorbed. Phase2,4chlorophenoxyacetic acid. 30, 1523-1527.
Published
2012-08-24
Issue
Section
License
Copyright (c) 2012 Authors and Global Journals Private Limited
This work is licensed under a Creative Commons Attribution 4.0 International License.