FTIR and Optical Absorption Studies Of New Magnesium Lead Borate Glasses
infrared spectroscopy, glass network formers, glass network modifiers, optical energy band gap, Urbach energy
Abstract
New magnesium lead borate glasses 10-x MgO-xMgCl2-40PbO-50B2O3 x 0 1 2 3 4 5 6 7 8 and 10 mole were prepared by melt quenching technique Fourier transform infrared spectroscopic studies revealed the presence of BO3 trigonal and BO4 tetrahedral structural units in these glasses The optical energy band gaps Urbach energies and theoretical refractive index values are reported No considerable structural changes with the composition are observed FTIR revealed the formation of NBOs and the behaviour of MgO as glass network modifier The expansion of B-O network with increasing x mole is attributed to the presence of Chlorine ions
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2012-03-15
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