Evaluation of Pure and Ag-Doped Tio2 Films in the Photocatalytic Activity of Phenol

Authors

  • Sonia M. A. Jorge

  • Adriana B. Araujo

  • Pedro M. Padilha

  • Doroteia F. Bozano

  • Gustavo R. Castro

TiO2 films, photocatalysis, doping, phenol, photodegradation

Abstract

Pure TiO 2 films, modified by the addition of Degussa P25 powder and Ag-doped were synthesized using sol-gel route and immobilized in borosilicate support at different withdrawing rates and dipping time. They were characterized by X-ray diffractometry, scanning electronic microscopy and high-resolution field-emission gun scanning electronic microscopy. Their photocatalytic activities under UV irradiation were examined using phenol. The higher activities were achieved through the Ag-doped films deposited with 0.4 mm s -1 and two dipping. Approximately 90% of the organic contaminant was photodegradated after 24 h of irradiation.

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How to Cite

Evaluation of Pure and Ag-Doped Tio2 Films in the Photocatalytic Activity of Phenol. (2015). Global Journal of Science Frontier Research, 15(B2), 17-23. https://www.journalofscience.org/index.php/GJSFR/article/view/1486

References

J Byrne, Pilar Fernandez-Ibañez, Patrick Dunlop, Dheaya Alrousan, Jeremy Hamilton (2011) Photocatalytic Enhancement for Solar Disinfection of Water: A Review. 2011, 1-12.

A Ibhadon, P Fitzpatrick (2013) Heterogeneous photocatalysis: Recent advances and applications. 3, 189-218.

Saber Ahmed, M Rasul, R Brown, M Hashib (2011) Influence of parameters on the heterogeneous photocatalytic degradation of pesticides and phenolic contaminants in wastewater: A short review. 92(3), 311-330.

G Giovanni, J Valente, P Padilha, S Jorge, M Saeki, A Florentino (2010) Polishing of water treated by a biological process with heterogeneous photocatalysis. 10, 731-737.

A Linsebigler, G Lu, J Yates (1995) Photocatalysis on TiO 2 surfaces: Principles, mechanisms, and selected results. 95, 735-758.

Umar Gaya, Abdul Abdullah (2008) Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide: A review of fundamentals, progress and problems. 9(1), 1-12.

Debabrata Chatterjee, Shimanti Dasgupta (2005) Visible light induced photocatalytic degradation of organic pollutants. 6(2-3), 186-205.

Lianfeng Zhang, Tatsuo Kanki, Noriaki Sano, Atsushi Toyoda (2003) Development of TiO2 photocatalyst reaction for water purification. 31(1), 105-110.

Silvia Gelover, Pedro Mondragón, Antonio Jiménez (2004) Titanium dioxide sol-gel deposited over glass and its application as a photocatalyst for water decontamination. 165(1-3), 241-246.

P Lu, F Wu, N Deng (2004) Enhancement of TiO 2 photocataytic redox ability by β-cyclodextrin in suspened solutions. 53, 87-93.

P Cozzoli, E Fanizza, R Camparelli, M Curri, A Agostiano (2004) Role of metal nanoparticles in TiO 2 /Ag nanocomposite-based microheterogeneous photocatalysis. 108, 9623-9630.

Chao Teh, Abdul Mohamed (2011) Roles of titanium dioxide and ion-doped titanium dioxide on photocatalytic degradation of organic pollutants (phenolic compounds and dyes) in aqueous solutions: A review. 509(5), 1648-1660.

Baifu Xin, Liqiang Jing, Zhiyu Ren, Baiqi Wang, Honggang Fu (2005) Effects of Simultaneously Doped and Deposited Ag on the Photocatalytic Activity and Surface States of TiO2. 109(7), 2805-2809.

Mantana Moonsiri, Pramoch Rangsunvigit, Sumaeth Chavadej, Erdogan Gulari (2004) Effects of Pt and Ag on the photocatalytic degradation of 4-chlorophenol and its by-products. 97(2-3), 241-248.

H Chao, Y Yun, H Xingfang, A Larbot (2003) Effect of silver doping on the phase transformation and grain growth of sol-gel titania powder. 23, 1457-1464.

D Shchukin, E Ustinovich, D Sviridov, P Pichat (2004) Effect of silver deposits on the photocatalytic activity of titanium dioxide for the removal of 2-chorophenol in water. 3, 142-144.

C He, Y Yun, X Hu, A Larbot (2002) Influence of silver doping on the photocatalytic activity of titania films. 200, 239-247.

D Bozano (2003) Preparação e caracterização de catalisadores de V 2 O 5 sobre suportes mistos de TiO 2 -SiO 2 obtidos pelo método sol-gel: oxidação de metano e diclorometano.

Ganesh Balasubramanian, Dionysios Dionysiou, Makram Suidan, Isabelle Baudin, Jean-Michel Laı̂né (2004) Evaluating the activities of immobilized TiO2 powder films for the photocatalytic degradation of organic contaminants in water. 47(2), 73-84.

Jing Liqiang, Sun Xiaojun, Cai Weimin, Xu Zili, Du Yaoguo, Fu Honggang (2003) The preparation and characterization of nanoparticle TiO2/Ti films and their photocatalytic activity. 64(4), 615-623.

G Balasubramanian, D Dionysiou, M Suidan, V Subramanian, I Baudin, J-M Laîné (2003) Titania powder modified sol-gel process for photocatalytic applications. 38(4), 823-831.

R Sonawane, S Hegde, M Dongare (2002) Preparation of titanium(IV) oxide thin film photocatalyst by sol-gel dip coating. 77(3), 744-750.

G Pecchi, P Reyes, P Sanhueza, J Villaseñor (2001) Photocatalytic degradation of pentachlorophenol on TiO2 sol-gel catalysts. 43(2), 141-146.

B Sankapal, M Lux-Steiner, A Ennaoui (2005) Synthesis and characterization of anatase-TiO2 thin films. 239(2), 165-170.

B Cullity (1978) Elements of X-ray Diffraction.

Evaluation of Pure and Ag-Doped Tio2 Films in the Photocatalytic Activity of Phenol

Published

2015-04-25

How to Cite

Evaluation of Pure and Ag-Doped Tio2 Films in the Photocatalytic Activity of Phenol. (2015). Global Journal of Science Frontier Research, 15(B2), 17-23. https://www.journalofscience.org/index.php/GJSFR/article/view/1486